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A number of processes could cause the parent substance to be depleted at the top of the magma chamber, or the daughter product to be enriched, both of which would cause the lava erupting earlier to appear very old according to radiometric dating, and lava erupting later to appear younger.
Geologists assert that older dates are found deeper down in the geologic column, which they take as evidence that radiometric dating is giving true ages, since it is apparent that rocks that are deeper must be older.
But even if it is true that older radiometric dates are found lower down in the geologic column, which is open to question, this can potentially be explained by processes occurring in magma chambers which cause the lava erupting earlier to appear older than the lava erupting later.
But at the same time, it will be enriched in the elements contained in the later forming minerals, namely sodium and potassium.
Further, the silicon content of the melt becomes enriched toward the latter stages of crystallization.